;ODYSSEUS ;Pulse sequence code for the acquisition of: 1H decoupled, 13C filtered, 19F spectra ;DEveloped by Methodology NMR Group ;University of Manchester ;Avance II+/III Version ;$CLASS=HighRes ;$DIM=2D ;$TYPE= ;$SUBTYPE= ;$COMMENT= #include #include #include "p2=p1*2" "p4=p3*2" "d2=1s/(cnst2*2)" "d11=30m" "d12=20u" "d19=p3+d12" "d0=3u" "DELTA1=d2-p16-d16-50u" "DELTA2=d2-p16-d16-50u-2*p3" "in0=inf1/2" 1 ze d11 pl16:f3 2 30m do:f3 d1 d12 pl1:f1 pl2:f2 (p1 ph1):f1 50u UNBLKGRAD DELTA1 p16:gp1 d16 (p2 ph2):f1 (p3 ph4):f2 p16:gp1 d16 DELTA2 50u BLKGRAD (p3 ph5):f2 d19 d0 (center (p2 ph3):f1 (p4 ph6):f2) d0 (p3 ph7):f2 d12 pl16:f3 go=2 ph31 cpd3:f3 30m do:f3 mc #0 to 2 F1PH(calph(ph7, +90), caldel(d0, +in0)) exit ph1=0 0 0 0 1 1 1 1 2 2 2 2 3 3 3 3 ph2=0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ph3=0 0 0 0 2 2 2 2 0 0 0 0 2 2 2 2 ph4=0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 ph5=0 0 2 2 0 0 2 2 0 0 2 2 0 0 2 2 ph6=0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ph7=0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ph31=0 0 0 0 1 1 1 1 2 2 2 2 3 3 3 3 ;pl1 : f1 channel - power level for pulse (default) ;pl2 : f2 channel - power level for pulse (default) ;pl3 : f3 channel - power level for pulse (default) ;pl12: f2 channel - power level for CPD/BB decoupling ;pl16: f3 channel - power level for CPD/BB decoupling ;p1 : f1 channel - 90 degree high power pulse ;p2 : f1 channel - 180 degree high power pulse ;p3 : f2 channel - 90 degree high power pulse ;p4 : f2 channel - 180 degree high power pulse ;p16: gradient pulse [1 msec] ;d1 : relaxation delay; 1-5 * T1 ;d0 : incremented delay (2D) [3 usec] ;d2 : 1/(2J(FC)) ;cnst2: = one bond J(FC) ;ns: 2*n ;ds: 4 ;for z-only gradients: ;gpz1: 35% CTP ;FnMODE: States ;use gradient files: ;gpnam1: SMSQ10.100